Project Details Solubility of volatile and gaseous fluorides in all solvents (Solubility Data Series)

Project No.:
2001-052-1-500
Start Date:
01 January 2002
End Date:
29 June 2005
Division Name:
Analytical Chemistry Division
Division No.:
500

Objective

 (previous 581/15/89) Series: Solubility Data Series; editor-in-chief: Mark Salomon

A critical evaluated collection of solubility data of the fluorides of xenon, boron, nitrogen, sulfur and carbon in all solvents, including XeF’s, BF3, NF3, N2F4, SF6, CF4, CHF3, CH2F2, CH3F, C2F6, C2HF5, C2H2F4, C2H3F3, C2H4F2, C2H5F, C2F4, C2H2F2, C2H3F, C3F8, C3F6, c-C4F8, C2F6O (ether), C3F6O (oxirane).

Description

A literature search for solubility data of the compounds XeF6, XeF4, XeF2, BF3, NF3, N2F4, SF6, CF4, CHF3, CH2F2, CH3F, C2F6, C2HF5, C2H2F4, C2H3F3, C2H4F2, C2H5F, C3F8, c-C4F8, C2H3F, C2H2F2, C2F4, C3F6, SiF4 and a few other compounds in all solvents is at least 85 % complete. So far approximately 350 systems have been compiled in rough draft and near 200 have been prepared in final draft. For systems for which data are available from several laboratories a critical evaluation will be prepared giving tables, equations and figures showing the recommended and tentative data. The volume should be of use to workers in environmental chemistry, industry, engineering and theoreticians in solution theory.

Progress

Status in Jan 2003 – Most data compilations are complete. There is good progress on gas +- water evaluations, other evaluations will get underway soon. All recent papers between 1988 and 2002 (also covering gas +- seawater ) have been collected and will be included in the review.

Volume 80 in the IUPAC-NIST Solubility Data Series. is to be published in J. Phys. Chem. Ref. Data 2005.

Published as Volume 80 in of the IUPAC-NIST Solubility Data Series. in J. Phys. Chem. Ref. Data 2005, 34, No. 1, 201-438.

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